Thanks Jochen and Geronimo
My name's Grant:)
So to clarify:
1) The dubmleator kit I used is stand alone and housed in its own little metal chassis case. It is powered by a VPump. Accordingly, it is powered by a simple 12vdc plug pack wall wart adapter. As it is DC powered I figured the VPump circuit didn't need to be attached to chassis or anything. I simply connected the high voltage output of the VPump to the Dubleator's B+ input and -input.
2) The dumbleator's PCB Rground, Sground, and Ground all seem to be connected on the PCB itself. I had always been told (and Geronimo your explanation of different grounds was very helpful thanks) - that there should be only one audio star ground point (with the exception that if a circuit is powered by a 240vac transformer the mains power should have its own earth point on the chassis). So Given this, as Rground, Sground and Ground were all connected on the PCB, I simply connected at one of these points and attached this to the sleeve of the dumbleator's output socket that touches the chassis.
3) The fender circuit I used was a Deluxe Reverb. I am not sure if its possible to attach schematics in this forum and I couldn't find a way to attach one but the fender AB763 circuit has a point where a 0.1uf capacitor comes out of the preamp section and meets a 0.001uf coupling capacitor which is the beggining of the phase inverter. I cut the circuit at the connect of these two caps in the amp and installed two 6.5mm jacks into the back of the amp - ie an output of the 0.1uf preamp capacitor being the "send" and the input of the 0.001uf coupling phase inverter cap being the "return" socket. Ie I installed a passive effects loop at these points. From there I plugged the dubmleator into the amp via tow guitar pedal patch leads.
This setup has created the ground loop. Even as I touch the guitar strings the buzzing sounds changes. I'm just not sure what I'e done wrong in the fender circuit to create this ground loop.
Thanks for all your help. I am very grateful:)